In the framework of the quasiparticle-phonon model, we study the non-statistical proton decay of excited states in odd nuclei towards low-lying collective states. Partial cross sections and branching ratios for the proton decay of the high angular momentum states in $^{41}$Sc, $^{59}$Cu and $^{91}$Nb %{\it excited by means of the ($^{7}$Li,$^{6}$He) reaction} are evaluated. The calculated branching ratios predict strong direct proton decays to the low-lying vibrational states in $^{41}$Sc and $^{91}$Nb. A general agreement with existing experimental data is found.